His father was Joseph de Ayala, and his mother was Isabel de Ochoa.
In 1714, he requested a dispensation to marry Josefa Francisca de Treviño. Dispensation source: Guerra, et. al., Index to the Marriage Investigations of the Diocese of Guadalajara, p.56.
Pedro Leonicio de Ayala. He married Clara Maria Guerra, daughter of Juan Guerra Cañamar and Juana Flores de Abrego.