He married Juana de Aguirre, daughter of Nicolas de Aguirre and Jacinta Gonzalez de Paredes.
Geronima Molano. She married Andres Galindo, son of Juan Galindo and Maria Ines de los Santos Coy on 7 Jan 1704 in Saltillo.
Luis Martin Molano. He married Margarita de Valdez.
Maria Rosa Molano. She married Juan Antonio Polanco.